The true meaning of isothermal

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On the Physical Meaning of the Isothermal Titration Calorimetry Measurements in Calorimeters with Full Cells

We have performed a detailed study of the thermodynamics of the titration process in an isothermal titration calorimeter with full cells. We show that the relationship between the enthalpy and the heat measured is better described in terms of the equation Delta H = W(inj) + Q (where W(inj) is the work necessary to carry out the titration) than in terms of DeltaH = Q. Moreover, we show that the ...

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ژورنال

عنوان ژورنال: Journal of Chemical Education

سال: 1990

ISSN: 0021-9584,1938-1328

DOI: 10.1021/ed067p630.1